A Product Formed from Glycylglycine in the Presence of Vanadate and Hydrogen Peroxide: The (Glycylde-N-hydroglycinato-kappa(3)N(2),N(N)(),O(1))oxoperoxovanadate(V) Anion

Frederick W. B. Einstein; Raymond J. Batchelor; Sarah J. Angus-Dunne; Alan S. Tracey

doi:10.1021/ic951007y

A Product Formed from Glycylglycine in the Presence of Vanadate and Hydrogen Peroxide: The (Glycylde-N-hydroglycinato-kappa(3)N(2),N(N)(),O(1))oxoperoxovanadate(V) Anion

Inorg Chem. 1996 Mar 13;35(6):1680-1684. doi: 10.1021/ic951007y.

Authors

Frederick W. B. Einstein¹, Raymond J. Batchelor, Sarah J. Angus-Dunne, Alan S. Tracey

Affiliation

¹ Department of Chemistry, Simon Fraser University, Burnaby, BC V5A 1S6, Canada.

PMID: 11666391
DOI: 10.1021/ic951007y

Abstract

A crystalline glycylglycine complex of monoperoxovanadate has been obtained and its X-ray structure determined. The coordination is pentagonal bipyramidal with the peroxo group and a tridentate glycylglycine occupying the equatorial positions. The axial positions of the anion are occupied by the oxo ligand and by one oxygen of the peroxo group of the adjacent anion. The latter interaction establishes the seventh bond and produces a dimeric structure in the crystalline material. NMR studies of its dissolution in water combined with previously reported results from equilibrium measurements show that the dimer dissociates in water to the monomeric precursor. It is proposed that this monomer corresponds to the complex responsible for the inhibition of the vanadium-catalyzed decomposition of hydrogen peroxide by glycylglycine. Crystal structure of [NEt(4)][VO(O(2))(GlyGly)].1.58H(2)O: monoclinic, space group P2(1); Z = 4; a = 10.618(2) Å; b = 14.803(2) Å; c = 11.809(2) Å; beta = 101.37(2) degrees; V = 1819.7 Å(3); T = 198 K; R(F)() = 0.029 for 2664 data (I(o) >/= 2.5sigma(I(o))) and 431 variables.