[Cu(L)Mn(N3)2]n: the first complex containing both macrocyclic oxamido and alternate (mu-1,1 and mu-1,3) azido bridges

Shi-bin Wang; Guang-ming Yang; Dai-zheng Liao; Li-cun Li

doi:10.1021/ic030085f

[Cu(L)Mn(N3)2]n: the first complex containing both macrocyclic oxamido and alternate (mu-1,1 and mu-1,3) azido bridges

Inorg Chem. 2004 Feb 9;43(3):852-4. doi: 10.1021/ic030085f.

Authors

Shi-bin Wang¹, Guang-ming Yang, Dai-zheng Liao, Li-cun Li

Affiliation

¹ Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China.

PMID: 14753803
DOI: 10.1021/ic030085f

Abstract

A wattle-type heteropolynuclear complex [(CuL)Mn(N(3))(2)](n) (1) (H(2)L = 2,3-dioxo-5,6:15,16-dibenzo-1,4,8,13-tetraazacyclo-pentadeca-7,13-diene), which represents the first system with macrocyclic oxamido and alternate azido bridges, forming a one-dimensional chain structure, has been synthesized and characterized by a low temperature magnetic study. The chains are stacked with interchain hydrogen and lead to the structure of a three-dimensional network.