Metal-mediated transformation of a triazinephenanthridinium ligand leading to a {Pd5} coordination complex observed crystallographically and by cryospray mass spectrometry

Inorg Chem. 2008 Mar 17;47(6):1883-5. doi: 10.1021/ic7022192. Epub 2008 Feb 14.

Abstract

The formation of a pentanuclear palladium(II) complex with a phenanthridinonetriazine-based ligand system, which itself is formed by a metal-mediated rearrangement of a triazinephenanthridinium proligand, is described.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray / methods
  • Freezing
  • Kinetics
  • Ligands
  • Mass Spectrometry / methods
  • Models, Molecular
  • Palladium / chemistry*
  • Phenanthridines / chemistry*
  • Triazines / chemistry*

Substances

  • Ligands
  • Phenanthridines
  • Triazines
  • Palladium