Palladium-based nanostructures with highly porous features and perpendicular pore channels as enhanced organic catalysts

Angew Chem Int Ed Engl. 2013 Feb 25;52(9):2520-4. doi: 10.1002/anie.201208901. Epub 2013 Jan 30.

Abstract

Channeling a good catalyst: Highly porous palladium nanostructures (pPdNs) with perpendicular pore channels were prepared under mild conditions. The combination of high surface area and rich edge/corner atoms gives pPdNs better catalytic performance than known Pd catalysts for the hydrogenation of nitrobenzene and styrene and the Suzuki coupling reaction.