Refractive indices of unfilled resin mixtures and cured composites related to color and translucency of conventional and low-shrinkage composites

J Biomed Mater Res B Appl Biomater. 2017 Jan;105(1):7-13. doi: 10.1002/jbm.b.33523. Epub 2015 Sep 15.

Abstract

This study correlated the refractive indices (RIs) of unfilled resin mixtures and resin-based composites (RBCs) with color and translucency of conventional and low-shrinkage RBCs. Unfilled resin mixtures based on different ratios of conventional monomers Bisphenol A-glycidyl-methacrylate (BisGMA)/triethyleneglycol-dimethacrylate (TEGDMA) and urethane-dimethacrylate (UDMA)/TEGDMA and a low-shrinkage monomer FIT-852 (FIT, Esstech Inc.)/TEGDMA were used to prepare model RBCs, containing 30 wt % of the organic matrix and 70 wt % of silanated barium-glass fillers (n = 1.553, Esstech Inc.). The RIs of resins were measured on an ABBE refractometer, those of cured RBCs using the Becke-line method in immersion oils. Color and translucency were determined using an AvaSpec-2048 (Avantes BV) spectrometer. The RIs of unfilled resin mixtures decreased with increasing amounts of TEGDMA. Cured RBCs had higher RIs than their respective resin mixtures. BisGMA-based composites were more translucent with significantly lower L* values than FIT- and UDMA-based RBCs. The RIs of unfilled resins positively correlated with cured RBCs (p = 0.001), as did the RIs with translucency (p = 0.001) and color (p = 0.008). Resin mixtures and corresponding RBCs based on UDMA and its modified low-shrinkage version, FIT, showed similar optical properties. The RIs of unfilled resins appeared to be good predictors of the RIs of cured RBCs. © 2015 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 105B: 7-13, 2017.

Keywords: color; composite; low-shrinkage; refractive index; translucency.

MeSH terms

  • Bisphenol A-Glycidyl Methacrylate / chemistry*
  • Methacrylates / chemistry*
  • Polyethylene Glycols / chemistry*
  • Polymethacrylic Acids / chemistry*
  • Polyurethanes / chemistry*
  • Refractometry*

Substances

  • Methacrylates
  • Polymethacrylic Acids
  • Polyurethanes
  • urethane dimethacrylate luting resin
  • triethylene glycol dimethacrylate
  • Polyethylene Glycols
  • Bisphenol A-Glycidyl Methacrylate