Spin Manipulation by Creation of Single-Molecule Radical Cations

Phys Rev Lett. 2016 Jan 15;116(2):027201. doi: 10.1103/PhysRevLett.116.027201. Epub 2016 Jan 15.

Abstract

All-trans-retinoic acid (ReA), a closed-shell organic molecule comprising only C, H, and O atoms, is investigated on a Au(111) substrate using scanning tunneling microscopy and spectroscopy. In dense arrays single ReA molecules are switched to a number of states, three of which carry a localized spin as evidenced by conductance spectroscopy in high magnetic fields. The spin of a single molecule may be reversibly switched on and off without affecting its neighbors. We suggest that ReA on Au is readily converted to a radical by the abstraction of an electron.