High yield synthesis of Ni-BTC metal-organic framework with ultrasonic irradiation: Role of polar aprotic DMF solvent

Farrukh Israr; Daye Chun; Yeongmin Kim; Duk Kyung Kim

doi:10.1016/j.ultsonch.2015.12.007

High yield synthesis of Ni-BTC metal-organic framework with ultrasonic irradiation: Role of polar aprotic DMF solvent

Ultrason Sonochem. 2016 Jul:31:93-101. doi: 10.1016/j.ultsonch.2015.12.007. Epub 2015 Dec 11.

Authors

Farrukh Israr¹, Daye Chun², Yeongmin Kim¹, Duk Kyung Kim³

Affiliations

¹ Department of Nuclear and Energy Engineering, Jeju National University, Jeju 690-756, Republic of Korea.
² Department of Chemistry, College of Chemistry, U. C. Berkeley, CA 94720, USA.
³ Department of Chemistry, Auburn University at Montgomery, Montgomery, AL 36117, USA. Electronic address: dkim@aum.edu.

PMID: 26964927
DOI: 10.1016/j.ultsonch.2015.12.007

Abstract

Nickel based porous solid was synthesized with 20 kHz ultrasonic irradiation. The reaction of Ni(II) nitrate hexahydrate with 1,3,5-benzene tricarboxylic acid in N,N-Dimethylformamide (DMF) as the sole solvent under ultrasonic radiation produced porous Ni-BTC MOF. Choice of correct solvent for the ultrasonic treatment was proven important. The effect of varying ultrasonic powers (40%, 60% and 80% of 750 W) along with different temperature conditions (50 °C, 60 °C, 70 °C and 80 °C) influenced the respective yield. A very high yield of 88% Ni-BTC MOF was obtained from 80% ultrasonic power at 60 °C. BET surface areas of the MOF crystals measured by N2 gas adsorption isotherms were in the range of 960-1000 m(2)/g.

Keywords: Ni-BTC MOF; Polar aprotic solvent; Power effect; Temperatures effect; Ultrasonic treatment.

Publication types

Research Support, Non-U.S. Gov't