Cation and anion optimization of ammonium halide for interfacial passivation of inverted perovskite solar cells

Hao Wu; Xinxing Yin; Lei Lu; Jiaxing Song; Lin Hu; Yingzhi Jin; Zhen Su; Jiefeng Hai; Zaifang Li

doi:10.1039/d3cc01195j

Cation and anion optimization of ammonium halide for interfacial passivation of inverted perovskite solar cells

Chem Commun (Camb). 2023 May 18;59(41):6183-6186. doi: 10.1039/d3cc01195j.

Authors

Hao Wu^{1

2}, Xinxing Yin^{1

3

4}, Lei Lu⁵, Jiaxing Song¹, Lin Hu¹, Yingzhi Jin¹, Zhen Su¹, Jiefeng Hai², Zaifang Li¹

Affiliations

¹ China-Australia Institute for Advanced Materials and Manufacturing (IAMM), Jiaxing University, Jiaxing 314001, China. xxyin@zjxu.edu.cn.
² Guangxi Colleges and Universities Key Laboratory of Surface and Interface Electrochemistry, Guilin University of Technology, Guilin, 541004, China. haijiefeng@glut.edu.cn.
³ Zhejiang Jinko Solar, Yuanhua Town, Haining, Zhejiang 314416, China.
⁴ Engineering Research Center of Alternative Energy Materials & Devices, Ministry of Education, Sichuan University, Chengdu 610065, China.
⁵ College of Biological, Chemical Science and Chemical Engineering, Jiaxing University, Jiaxing 314001, China.

PMID: 37128955
DOI: 10.1039/d3cc01195j

Abstract

Perovskite solar cell (PSC) commercialization faces intrinsic stability and efficiency challenges. N¹-phenylethane-1,2-diamine hydrohalides (PNEAX) based on a new design strategy featuring cation and anion optimization have been developed for efficient interfacial passivation. Among them, PNEACl-treated devices achieved a champion efficiency of 21.01% with good stability.