Bis[ S-octyl 3-(2-methyl-propyl-idene)di-thio-carb-az-ato-κ2N3, S]nickel(II)

Sultana Shakila Khan; Md Belayet Hossain Howlader; Md Chanmiya Sheikh; Ryuta Miyatake; Ennio Zangrando

doi:10.1107/S241431462400186X

Bis[ S-octyl 3-(2-methyl-propyl-idene)di-thio-carb-az-ato-κ²N³, S]nickel(II)

IUCrdata. 2024 Mar 6;9(Pt 3):x240186. doi: 10.1107/S241431462400186X. eCollection 2024 Mar.

Authors

Sultana Shakila Khan¹, Md Belayet Hossain Howlader¹, Md Chanmiya Sheikh², Ryuta Miyatake³, Ennio Zangrando⁴

Affiliations

¹ Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh.
² Department of Applied Science, Faculty of Science, Okayama University of Science, Japan.
³ Center for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama, 930-8555, Japan.
⁴ Department of Chemical and Pharmaceutical Sciences, University of Trieste, Italy.

Abstract

The central Ni^II atom in the title complex, [Ni(C₁₃H₂₅N₂S₂)₂], is located on an inversion center and adopts a roughly square-planar coordination environment defined by two chelating N,S donor sets of two symmetry-related ligands in a trans configuration. The Ni-N and Ni-S bond lenghts are 1.9193 (14) and 2.1788 (5) Å, respectively, with a chelating N-Ni-S bond angle of 86.05 (4)°. These data are compared with those measured for similar di-thio-carbazato ligands that bear n-octyl or n-hexyl alkyl chains. Slight differences are observed with respect to the phenyl-ethyl-idene derivative where the ligands are bound cis relative to one another.

Keywords: NiII complex; crystal structure; dithiocarbazato ligand; octyl alkyl chain; trans configuration complex.