Coupling of struvite crystallization and aqueous phase recirculation for hydrochar upgrading and nitrogen recovery during hydrothermal carbonization of sewage sludge

Le Gou; Liyi Dai; Yuanyuan Wang

doi:10.1016/j.scitotenv.2024.172682

Coupling of struvite crystallization and aqueous phase recirculation for hydrochar upgrading and nitrogen recovery during hydrothermal carbonization of sewage sludge

Sci Total Environ. 2024 Jun 15:929:172682. doi: 10.1016/j.scitotenv.2024.172682. Epub 2024 Apr 24.

Authors

Le Gou¹, Liyi Dai², Yuanyuan Wang³

Affiliations

¹ State Key Laboratory of Petroleum Molecular & Process Engineering, East China Normal University, No. 500 Dongchuan Road, Shanghai 200241, PR China; Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai 200062, PR China.
² State Key Laboratory of Petroleum Molecular & Process Engineering, East China Normal University, No. 500 Dongchuan Road, Shanghai 200241, PR China; Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai 200062, PR China. Electronic address: dai_liyi@163.com.
³ State Key Laboratory of Petroleum Molecular & Process Engineering, East China Normal University, No. 500 Dongchuan Road, Shanghai 200241, PR China; Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai 200062, PR China. Electronic address: ecnu_yywang@163.com.

PMID: 38663600
DOI: 10.1016/j.scitotenv.2024.172682

Abstract

Recycling of aqueous phase (AP) as a by-product after hydrothermal carbonization (HTC) of sewage sludge (SS) has been of interest. The combination of magnesium ammonium phosphate (MAP) or the so-called struvite crystallization and aqueous phase (AP) recirculation has great potential for resource recovery and hydrochar enhancement. In this study, both the aqueous phase of HTC after MAP recovery of NH₄⁺-N (AP-MAP) and the untreated aqueous phase of HTC (AP-HTC) were reused for HTC of fresh SS, and both aqueous phases were recycled four times. The effects of the two AP cycles on the properties of AP and hydrochar at 200, 230, and 260 °C were studied, and the effect of temperature on the two AP cycles was similar. The hydrochar produced by the AP-MAP cycle had lower nitrogen content than that of the AP-HTC cycle due to the low ammonia nitrogen (NH₄⁺-N) content, and the combustion performance was improved. MAP recovery reduces the accumulation of NH₄⁺-N in the AP cycle and MAP is also a high-quality fertilizer. Therefore, the combination of MAP recovery and AP recycling provides a feasible technical approach for resource utilization, eutrophic AP treatment, and production of high-quality hydrochar in the HTC process of SS.

Keywords: Aqueous phase recirculation; Hydrochar; Hydrothermal carbonization; Sewage sludge; Struvite crystallization.