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Base-catalyzed dehydration of 3-substituted benzene cis-1,2-dihydrodiols: stabilization of a cyclohexadienide anion intermediate by negative aromatic hyperconjugation.
Kudavalli JS, Rao SN, Bean DE, Sharma ND, Boyd DR, Fowler PW, Gronert S, Kamerlin SC, Keeffe JR, More O'Ferrall RA. Kudavalli JS, et al. Among authors: more o ferrall ra. J Am Chem Soc. 2012 Aug 29;134(34):14056-69. doi: 10.1021/ja304366j. Epub 2012 Aug 16. J Am Chem Soc. 2012. PMID: 22830996
Hyperaromatic stabilization of arenium ions.
Kudavalli JS, Boyd DR, Coyne D, Keeffe JR, Lawlor DA, MacCormac AC, More O'Ferrall RA, Rao SN, Sharma ND. Kudavalli JS, et al. Among authors: more o ferrall ra. Org Lett. 2010 Dec 3;12(23):5550-3. doi: 10.1021/ol1014027. Epub 2010 Nov 5. Org Lett. 2010. PMID: 21053960
14 results