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Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis.
Chem Rev. 2022 Jan 26;122(2):1485-1542. doi: 10.1021/acs.chemrev.1c00383. Epub 2021 Nov 18.
Chem Rev. 2022.
PMID: 34793128
Review.
Cross-Electrophile Coupling of Unactivated Alkyl Chlorides.
Sakai HA, Liu W, Le CC, MacMillan DWC.
Sakai HA, et al.
J Am Chem Soc. 2020 Jul 8;142(27):11691-11697. doi: 10.1021/jacs.0c04812. Epub 2020 Jun 26.
J Am Chem Soc. 2020.
PMID: 32564602
Free PMC article.
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Nontraditional Fragment Couplings of Alcohols and Carboxylic Acids: C(sp3)-C(sp3) Cross-Coupling via Radical Sorting.
Sakai HA, MacMillan DWC.
Sakai HA, et al.
J Am Chem Soc. 2022 Apr 13;144(14):6185-6192. doi: 10.1021/jacs.2c02062. Epub 2022 Mar 30.
J Am Chem Soc. 2022.
PMID: 35353531
Free PMC article.
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Alcohols as Alkylating Agents: Photoredox-Catalyzed Conjugate Alkylation via In Situ Deoxygenation.
Wang JZ, Sakai HA, MacMillan DWC.
Wang JZ, et al. Among authors: sakai ha.
Angew Chem Int Ed Engl. 2022 Aug 26;61(35):e202207150. doi: 10.1002/anie.202207150. Epub 2022 Jul 19.
Angew Chem Int Ed Engl. 2022.
PMID: 35727296
Free PMC article.
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Exploiting the Marcus inverted region for first-row transition metal-based photoredox catalysis.
Chan AY, Ghosh A, Yarranton JT, Twilton J, Jin J, Arias-Rotondo DM, Sakai HA, McCusker JK, MacMillan DWC.
Chan AY, et al. Among authors: sakai ha.
Science. 2023 Oct 13;382(6667):191-197. doi: 10.1126/science.adj0612. Epub 2023 Oct 12.
Science. 2023.
PMID: 37824651
Free PMC article.
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Direct Bioisostere Replacement Enabled by Metallaphotoredox Deoxydifluoromethylation.
Mao E, Prieto Kullmer CN, Sakai HA, MacMillan DWC.
Mao E, et al. Among authors: sakai ha.
J Am Chem Soc. 2024 Feb 28;146(8):5067-5073. doi: 10.1021/jacs.3c14460. Epub 2024 Feb 16.
J Am Chem Soc. 2024.
PMID: 38365186
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