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Proximal Pocket Hydrogen Bonds Significantly Influence the Mechanism of Chloroperoxidase Compound I Formation.
J Phys Chem B. 2015 Oct 1;119(39):12590-602. doi: 10.1021/acs.jpcb.5b06324. Epub 2015 Sep 18.
J Phys Chem B. 2015.
PMID: 26339752
Chloroperoxidase-Catalyzed Epoxidation of Cis-β-Methylstyrene: NH-S Hydrogen Bonds and Proximal Helix Dipole Change the Catalytic Mechanism and Significantly Lower the Reaction Barrier.
Morozov AN, Pardillo AD, Chatfield DC.
Morozov AN, et al. Among authors: pardillo ad.
J Phys Chem B. 2015 Nov 12;119(45):14350-63. doi: 10.1021/acs.jpcb.5b06731. Epub 2015 Nov 3.
J Phys Chem B. 2015.
PMID: 26452587
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