Preparation and characterisation of palladium, platinum and manganese di(organo)carbene complexes from quinolinone and quinolinium precursors

Dalton Trans. 2004 Feb 7:(3):413-20. doi: 10.1039/b314217p. Epub 2003 Dec 18.

Abstract

A series of palladium, platinum and manganese di(organo)carbene complexes have been prepared from 4-chloro-N-methylquinolinone by processes that involve alkylation before or after attachment to the metal unit; the nucleophilic heteroatoms are separated from the C-donor atom by three bonds.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Hydrocarbons
  • Manganese / chemistry*
  • Methane / analogs & derivatives*
  • Methane / chemistry*
  • Models, Molecular
  • Molecular Structure
  • Organometallic Compounds* / chemical synthesis
  • Organometallic Compounds* / chemistry
  • Palladium / chemistry*
  • Platinum / chemistry*
  • Quinolones / chemistry*

Substances

  • Hydrocarbons
  • Organometallic Compounds
  • Quinolones
  • carbene
  • Manganese
  • Platinum
  • Palladium
  • Methane