1d-1-O-tert-Butyl-diphenyl-silyl-2,3,6-O-tris-(meth-oxy-methyl-ene)-myo-inositol 4,5-bis-(dibenzyl-phosphate)

Regan J Anderson; Graeme J Gainsford

doi:10.1107/S1600536812008069

1d-1-O-tert-Butyl-diphenyl-silyl-2,3,6-O-tris-(meth-oxy-methyl-ene)-myo-inositol 4,5-bis-(dibenzyl-phosphate)

Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o900. doi: 10.1107/S1600536812008069. Epub 2012 Feb 29.

Authors

Regan J Anderson¹, Graeme J Gainsford

Affiliation

¹ Industrial Research Limited, PO Box 31-310, Lower Hutt, New Zealand.

Abstract

THE TITLE COMPOUND [SYSTEMATIC NAME: tetra-benzyl (1R,2R,3S,4R,5R,6S)-4-(tert-butyl-diphenyl-sil-yloxy)-3,5,6-tris-(meth-oxy-meth-oxy)cyclo-hexane-1,2-diyl bis-phosphate], C(56)H(68)O(15)P(2)Si, was isolated as an inter-mediate in the preparation of a phosphatidylinositol phosphate for biological studies. In the crystal, the mol-ecules are connected via one methyl-ene C-H⋯π and two weak phen-yl-ether C-H⋯O inter-actions. One benz-yloxy group is disordered over two overlapping positions with an occupancy ratio of 0.649 (7):0.351 (7).