Measures to endorse the adoption of eco-friendly biodegradable plastics as a response to the scale of plastic pollution has created a demand for innovative products from materials from Nature. Ionic liquids (ILs) have the ability to disrupt the hydrogen bonding network of biopolymers, increase the mobility of biopolymer chains, reduce friction, and produce materials with various morphologies and mechanical properties. Due to these qualities, ILs are considered ideal for plasticizing biopolymers, enabling them to meet a wide range of specifications for biopolymeric materials. This mini-review discusses the effect of different IL-plasticizers on the processing, tensile strength, and elasticity of materials made from various biopolymers (e.g., starch, chitosan, alginate, cellulose), and specifically covers IL-plasticized packaging materials and materials for biomedical and electrochemical applications. Furthermore, challenges (cost, scale, and eco-friendliness) and future research directions in IL-based plasticizers for biopolymers are discussed.
Keywords: biopolymers; ionic liquids; materials; plasticizer.