Evaluation of soil pesticide leaching to groundwater using undisturbed lysimeter: development of the pesticide groundwater leaching scoring system (PLS)

Abstract

Groundwater pesticide safety management is essential for providing consistently safe water for humans, but such management is limited globally. In this study, we developed an accurate and convenient exposure assessment method for the safety management of pesticides in groundwater by conducting a lysimeter experiment to evaluate the leaching of 11 pesticides into groundwater. During the experimental period, flutoalanil and oxadiazon had the highest cumulative leaching amounts, 603.7 and 83.5 ng, respectively. Comparative analysis of existing groundwater exposure prediction indices, including the GUS, LEACH, modified LEACH, Hornsby index, and GLI showed no correlations with the measured data (p > 0.05). To enhance the accuracy of the assessment method, we used lysimeter data and principal component analysis to determine the main factors affecting groundwater leaching, and developed the "pesticide groundwater leaching scoring system" (PLS). The soil and water half-life, which had the greatest positive impact on groundwater leaching, was set as a 10-point indicator, whereas log P was set as a 1-point indicator. In contrast, solubility in water was determined as a 5-point indicator, and organic carbon partition coefficient and vapor pressure were determined as 2.5-point indicators owing to their negative relationship. The correlation coefficient was 0.670, indicating a significant correlation with the lysimeter data (p < 0.05). Using our scoring system, we ranked 376 pesticides. As an exposure assessment method developed using actual data, the PLS is expected to be applicable to groundwater safety management.

Keywords: Exposure assessment; Groundwater; Leaching; Lysimeter; Pesticide groundwater leaching scoring system (PLS).