The activation and utilization of challenging aliphatic alcohols like methanol and ethanol is a very appealing approach to synthesize valuable organic molecules. Utilization of methanol and ethanol as a coupling partner has emerged as a valuable alternative to synthesize industrially relevant N-heterocycles because they can be easily procured from renewable sources unlike other activated coupling partners which are expensive and also unstable. Herein, a mild and metal-free photocatalytic protocol to synthesize quinazolinones and more challenging benzothiadiazine-1,1-dioxides, which is unprecedented at room temperature, is demonstrated. This methodology showcased broad substrate scope and provided important N-heterocycles more efficiently than the transition metal-based high temperature protocols. An unexplored reactivity with allyl alcohol is observed following the developed protocol. A series of control experiments were carried out to understand the mechanism.